Effect of Core–Shell Rubber Nanoparticles on the Mechanical Properties of Epoxy and Epoxy-Based CFRP

• Published in: Materials 2022-10, Vol.15 (21), p.7502
• Main Authors: Glaskova-Kuzmina, Tatjana, Stankevics, Leons, Tarasovs, Sergejs, Sevcenko, Jevgenijs, Špaček, Vladimir, Sarakovskis, Anatolijs, Zolotarjovs, Aleksejs, Shmits, Krishjanis, Aniskevich, Andrey
• Format: Article
• Language: English
• Subjects: Additives; Analysis; Carbon fiber reinforced plastics; Carbon fibers; Carbon-epoxy composites; Crack initiation; Crack propagation; Emulsion polymerization; Epoxy resins; Fiber reinforced polymers; Fillers; Fracture toughness; Fractures; Glass transition temperature; Manufacturing; Mechanical properties; Modulus of elasticity; Morphology; Nanoparticles; Rubber; Temperature; Tensile properties; Tensile strength
• ISSN: 1996-1944; 1996-1944
• DOI: 10.3390/ma15217502

The aim of the research was to estimate the effect of core–shell rubber (CSR) nanoparticles on the tensile properties, fracture toughness, and glass transition temperature of the epoxy and epoxy-based carbon fiber reinforced polymer (CFRP). Three additives containing CSR nanoparticles were used for the research resulting in a filler fraction of 2–6 wt.% in the epoxy resin. It was experimentally confirmed that the effect of the CSR nanoparticles on the tensile properties of the epoxy resin was notable, leading to a reduction of 10–20% in the tensile strength and elastic modulus and an increase of 60–108% in the fracture toughness for the highest filler fraction. The interlaminar fracture toughness of CFRP was maximally improved by 53% for ACE MX 960 at CSR content 4 wt.%. The glass transition temperature of the epoxy was gradually improved by 10–20 °C with the increase of CSR nanoparticles for all of the additives. A combination of rigid and soft particles could simultaneously enhance both the tensile properties and the fracture toughness, which cannot be achieved by the single-phase particles independently.