High Piezoelectric Output Voltage from Blue Fluorescent N,N-Dimethyl-4-nitroaniline Nano Crystals in Poly-L-Lactic Acid Electrospun Fibers

• Published in: Materials 2022-11, Vol.15 (22), p.7958
• Main Authors: Baptista, Rosa Maria Ferreira, Silva, Bruna, Oliveira, João, Bayzi Isfahani, Vahideh, Almeida, Bernardo, Pereira, Mário R., Cerca, Nuno, Castro, Cidália, Rodrigues, Pedro, Machado, A. V., Belsley, M., de Matos Gomes, Etelvina
• Format: Article
• Language: English
• Subjects: Charge transfer; Ciências Físicas; Ciências Naturais; Collectors; Crystals; Decay; Elastic properties; Electric potential; Electrospinning; Emitters; Energy harvesting; Engenharia dos Materiais; Engenharia e Tecnologia; Fluorescence; functional organic materials; Hybrid systems; Microfibers; Modulus of elasticity; Nanocrystals; nitroanilines; Optical properties; Optics; Organic chemistry; Perovskites; piezoelectric crystals; Piezoelectricity; Polylactic acid; Polymers; Radiation; Science & Technology; Solid state; Superelasticity; Superplasticity; Tensile strength; Voltage
• ISSN: 1996-1944; 1996-1944
• DOI: 10.3390/ma15227958

N,N-dimethyl-4-nitroaniline is a piezoelectric organic superplastic and superelastic charge transfer molecular crystal that crystallizes in an acentric structure. Organic mechanical flexible crystals are of great importance as they stand between soft matter and inorganic crystals. Highly aligned poly-l-lactic acid polymer microfibers with embedded N,N-dimethyl-4-nitroaniline nanocrystals are fabricated using the electrospinning technique, and their piezoelectric and optical properties are explored as hybrid systems. The composite fibers display an extraordinarily high piezoelectric output response, where for a small stress of 5.0 × 103 Nm−2, an effective piezoelectric voltage coefficient of geff = 4.1 VmN−1 is obtained, which is one of the highest among piezoelectric polymers and organic lead perovskites. Mechanically, they exhibit an average increase of 67% in the Young modulus compared to polymer microfibers alone, reaching 55 MPa, while the tensile strength reaches 2.8 MPa. Furthermore, the fibers show solid-state blue fluorescence, important for emission applications, with a long lifetime decay (147 ns) lifetime decay. The present results show that nanocrystals from small organic molecules with luminescent, elastic and piezoelectric properties form a mechanically strong hybrid functional 2-dimensional array, promising for applications in energy harvesting through the piezoelectric effect and as solid-state blue emitters. This research was funded by Fundação para a Ciência e Tecnologia through FEDER (European Fund for Regional Development)-COMPETE-QREN-EU (ref. UID/FIS/04650/2013 and UID/FIS/04650/2019) and E-Field - "Electric-Field Engineered Lattice Distortions (E-FiELD) for optoelectronic devices", ref. PTDC/NAN-MAT/0098/2020.