Cadmium Sulfide-Reinforced Double-Shell Microencapsulated Phase Change Materials for Advanced Thermal Energy Storage

• Published in: Polymers 2022-12, Vol.15 (1), p.106
• Main Authors: Zhang, Shendao, Zhu, Yucao, Zhang, Huanzhi, Xu, Fen, Sun, Lixian, Xia, Yongpeng, Lin, Xiangcheng, Peng, Hongliang, Ma, Lei, Li, Bin, Yan, Erhu, Huang, Pengru
• Format: Article
• Language: English
• Subjects: Alternative energy sources; Cadmium; Cadmium sulfide; Electron microscopy; Electronic devices; Energy conversion efficiency; Energy storage; Energy utilization; Enthalpy; Force and energy; Formaldehyde; Fourier transforms; Heat conductivity; Heat storage; Leakage; Melamine; Microscopy; Nanoparticles; Phase change materials; Phase transitions; Photothermal conversion; Polymers; Product development; Shells (structural forms); Smart materials; Sodium; Solar energy; Solar heating; Storage capacity; Sulfides; Temperature; Textiles; Thermal conductivity; Thermal cycling; Thermal energy; Thermal stability
• ISSN: 2073-4360; 2073-4360
• DOI: 10.3390/polym15010106

Phase change materials (PCMs) are widely used to improve energy utilization efficiency due to their high energy storage capacity. In this study, double-shell microencapsulated PCMs were constructed to resolve the liquid leakage issue and low thermal conductivity of organic PCMs, which also possess high thermal stability and multifunctionality. We used assembly to construct an inorganic-organic double shell for microencapsulate PCMs, which possessed the unprecedented synergetic properties of a cadmium sulfide (CdS) shell and melamine-formaldehyde polymeric shell. The scanning electron microscopy (SEM) and transmission electron microscopy (TEM) images confirmed the well-designed double-shell structure of the microcapsules, and the CdS was successfully assembled as the second shell on the surface of the polymer shell. The differential scanning calorimeter (DSC) showed that the double-shell microcapsules had a high enthalpy of 114.58 J/g, which indicated almost no changes after experiencing 100 thermal cycles, indicating good thermal reliability. The microcapsules also showed good shape stability and antileakage performance, which displayed no shape change and leakage after heating at 60 °C for 30 min. In addition, the photothermal conversion efficiency of the double-shell microcapsules reached 91.3%. Thus, this study may promote the development of microencapsulated PCMs with multifunctionality, offering considerable application prospects in intelligent temperature management for smart textiles and wearable electronic devices in combination with their solar thermal energy conversion and storage performance.