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Catalytic Ozonation of Aqueous Solution of Paracetamol
The catalytic properties of iron ions in the oxidative destruction of the active pharmaceutical ingredient paracetamol, in the presence of hydrogen peroxide have been investigated. It was found that in the presence of a homogeneous catalyst, the oxidation degree reaches more than 98%. The dependence...
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Published in: | Russian journal of general chemistry 2022, Vol.92 (13), p.3020-3024 |
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container_title | Russian journal of general chemistry |
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description | The catalytic properties of iron ions in the oxidative destruction of the active pharmaceutical ingredient paracetamol, in the presence of hydrogen peroxide have been investigated. It was found that in the presence of a homogeneous catalyst, the oxidation degree reaches more than 98%. The dependence of the oxidation efficiency on the concentration of the catalysts (hydrogen peroxide and ferrous ions) has been determined. A scheme for the treatment of pharmaceutical effluents is proposed, including the stages of homogeneous ozonation, coagulation of oxidative destruction and filtration products, and adsorption on activated carbon. The concentration of paracetamol and the chemical oxygen demand in the model solutions after treatment does not exceed the maximum permissible levels. |
doi_str_mv | 10.1134/S1070363222130023 |
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A. ; Karataeva, P. R.</creator><creatorcontrib>Ivantsova, N. A. ; Karataeva, P. R.</creatorcontrib><description>The catalytic properties of iron ions in the oxidative destruction of the active pharmaceutical ingredient paracetamol, in the presence of hydrogen peroxide have been investigated. It was found that in the presence of a homogeneous catalyst, the oxidation degree reaches more than 98%. The dependence of the oxidation efficiency on the concentration of the catalysts (hydrogen peroxide and ferrous ions) has been determined. A scheme for the treatment of pharmaceutical effluents is proposed, including the stages of homogeneous ozonation, coagulation of oxidative destruction and filtration products, and adsorption on activated carbon. The concentration of paracetamol and the chemical oxygen demand in the model solutions after treatment does not exceed the maximum permissible levels.</description><identifier>ISSN: 1070-3632</identifier><identifier>EISSN: 1608-3350</identifier><identifier>DOI: 10.1134/S1070363222130023</identifier><identifier>PMID: 36852346</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Acetaminophen ; Activated carbon ; Adsorption ; Aqueous solutions ; Catalysts ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Coagulation ; Ferrous ions ; Hydrogen peroxide ; Oxidation ; Ozonization ; Pharmaceuticals ; Purification ; Sewage</subject><ispartof>Russian journal of general chemistry, 2022, Vol.92 (13), p.3020-3024</ispartof><rights>Pleiades Publishing, Ltd. 2022</rights><rights>Pleiades Publishing, Ltd. 2022.</rights><rights>COPYRIGHT 2022 Springer</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c419t-2f5f6ca56370c3639d911b117117139b5cecc6e71e1932d9e1c49e8c582be5d73</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,776,780,881,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/36852346$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Ivantsova, N. A.</creatorcontrib><creatorcontrib>Karataeva, P. R.</creatorcontrib><title>Catalytic Ozonation of Aqueous Solution of Paracetamol</title><title>Russian journal of general chemistry</title><addtitle>Russ J Gen Chem</addtitle><addtitle>Russ J Gen Chem</addtitle><description>The catalytic properties of iron ions in the oxidative destruction of the active pharmaceutical ingredient paracetamol, in the presence of hydrogen peroxide have been investigated. It was found that in the presence of a homogeneous catalyst, the oxidation degree reaches more than 98%. The dependence of the oxidation efficiency on the concentration of the catalysts (hydrogen peroxide and ferrous ions) has been determined. A scheme for the treatment of pharmaceutical effluents is proposed, including the stages of homogeneous ozonation, coagulation of oxidative destruction and filtration products, and adsorption on activated carbon. The concentration of paracetamol and the chemical oxygen demand in the model solutions after treatment does not exceed the maximum permissible levels.</description><subject>Acetaminophen</subject><subject>Activated carbon</subject><subject>Adsorption</subject><subject>Aqueous solutions</subject><subject>Catalysts</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Coagulation</subject><subject>Ferrous ions</subject><subject>Hydrogen peroxide</subject><subject>Oxidation</subject><subject>Ozonization</subject><subject>Pharmaceuticals</subject><subject>Purification</subject><subject>Sewage</subject><issn>1070-3632</issn><issn>1608-3350</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp1UVtrFDEYDaLYWv0BvsiCL75MzZfMJJMXYVlsFQoVqs8hm_lmTZlJajJTqL_eb9herBcSSMi5JCeHsdfAjwFk_f4CuOZSSSEESM6FfMIOQfG2krLhT2lPcLXgB-xFKZecA-dKPGcHUrWNkLU6ZGrjJjfcTMGvzn-m6KaQ4ir1q_WPGdNcVhdpmO_OvrjsPE5uTMNL9qx3Q8FXt-sR-3by8evmU3V2fvp5sz6rfA1mqkTf9Mq7RknNPT3EdAZgC6CXKc228ei9Qg0IRorOIPjaYOubVmyx6bQ8Yh_2vlfzdsTOY5yyG-xVDqPLNza5YB8jMXy3u3RtjanJxJDBu1uDnChSmewYisdhcHHJZ4VuuVaqkZKob_-gXqY5R4pHLG2gBmj1A2vnBrQh9onu9YupXWvZiramKoh1_A8WjQ7H4FPEPtD5IwHsBT6nUjL29xmB26Vs-1fZpHnz--fcK-7aJYLYEwpBcYf5IdH_XX8Btr-wng</recordid><startdate>2022</startdate><enddate>2022</enddate><creator>Ivantsova, N. 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subjects | Acetaminophen Activated carbon Adsorption Aqueous solutions Catalysts Chemistry Chemistry and Materials Science Chemistry/Food Science Coagulation Ferrous ions Hydrogen peroxide Oxidation Ozonization Pharmaceuticals Purification Sewage |
title | Catalytic Ozonation of Aqueous Solution of Paracetamol |
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