Synthesis of 2-aryl-4,6-dinitrobenzo[d]isothiazolium from 2,4,6-trinitrotoluene

A method for the synthesis of previously unknown 2-aryl-4,6-dinitrobenzo[ d ]isothiazolium has been developed based on the replacement of ortho -NO 2 in N -(2,4,6-trinitrobenzylidene)anilines by treatment with PhCH 2 SH/K 2 CO 3 followed by conversion of the resulting N -(2-benzylthio-4,6-dinitroben...

Full description

Saved in:
Bibliographic Details
Main Authors: Sapozhnikov, Oleg Yu, Mezhnev, Vasily V, Smirnova, Elena V, Kimel, Boris G, Dutov, Mikhail D, Shevelev, Svyatoslav A
Format: Article
Language:
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:A method for the synthesis of previously unknown 2-aryl-4,6-dinitrobenzo[ d ]isothiazolium has been developed based on the replacement of ortho -NO 2 in N -(2,4,6-trinitrobenzylidene)anilines by treatment with PhCH 2 SH/K 2 CO 3 followed by conversion of the resulting N -(2-benzylthio-4,6-dinitrobenzylidene)anilines with SO 2 Cl 2 .
ISSN:0959-9436
1364-557X