Monitoring adsorption-induced switching by 129Xe NMR spectroscopy in a new metal-organic framework Ni2(2,6-ndc)2(dabco)Electronic supplementary information (ESI) available: FT-IR-spectra, thermogravimetric analysis, H2 adsorption. CCDC reference number 760964. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c003835k

• Main Authors: Klein, Nicole, Herzog, Christin, Sabo, Michal, Senkovska, Irena, Getzschmann, Jürgen, Paasch, Silvia, Lohe, Martin R, Brunner, Eike, Kaskel, Stefan
• Format: Article
• Language: English
• ISSN: 1463-9076; 1463-9084
• DOI: 10.1039/c003835k

The synthesis and structure of a new flexible metal-organic framework Ni 2 (2,6-ndc) 2 (dabco) (DUT-8(Ni), DUT = Dresden University of Technology, 2,6-ndc = 2,6-naphthalenedicarboxylate, dabco = 1,4-diazabicyclo[2.2.2]octane) as well as its characterization by gas adsorption and 129 Xe NMR spectroscopy is described. The compound shows reversible structural transformation without loss of crystallinity upon solvent removal and physisorption of several gases. Xenon adsorption studies combined with 129 Xe NMR spectroscopy turn out to be favorable methods for the detection and characterization of the so-called "gate-pressure" effect in this novel MOF material. The linewidth and chemical shift of the 129 Xe NMR signal are shown to be very sensitive parameters for the detection of this structural transition from a narrow pore system with low porosity to a wide pore state. The transition and threshold temperature is clearly detected. Simultaneous xenon adsorption and 129 Xe NMR spectroscopy shows the gate opening and structural changes in a new microporous metal-organic framework.