Highly efficient aerobic oxidation of alkenes over unsupported nanogoldElectronic supplementary information (ESI) available: Experimental protocols for characterizations and catalytic evaluations, TEM, FTIR, XPS and catalytic data. See DOI: 10.1039/c0cc00664e

An octylsilane-stabilized colloidal dispersion of 2 nm crystalline gold nanoparticles is highly active and selective for the aerobic oxidations of stilbene and cyclohexene in methylcyclohexane. An n -octylsilane stabilized colloidal solution of gold nanoparticles is the best catalyst to date for the...

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Main Authors: Boualleg, Malika, Guillois, Kevin, Istria, Bertrand, Burel, Laurence, Veyre, Laurent, Basset, Jean-Marie, Thieuleux, Chloé, Caps, Valérie
Format: Article
Language:English
Online Access:Get full text
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Summary:An octylsilane-stabilized colloidal dispersion of 2 nm crystalline gold nanoparticles is highly active and selective for the aerobic oxidations of stilbene and cyclohexene in methylcyclohexane. An n -octylsilane stabilized colloidal solution of gold nanoparticles is the best catalyst to date for the aerobic epoxidation of trans -stilbene.
ISSN:1359-7345
1364-548X
DOI:10.1039/c0cc00664e