"On-water" conjugate additions of anilinesElectronic supplementary information (ESI) available: General experimental procedures and spectroscopic data for all synthesized compounds. See DOI: 10.1039/c0cc02502j

The conjugate addition of anilines onto unsaturated ketones, esters and N -acylpyrroles was investigated. Based on a recently proposed explanation for the phenomenon of on-water catalysis, operationally simple and mild reaction conditions for effecting these addition reactions have been developed. T...

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Bibliographic Details
Main Authors: Phippen, Christopher B. W, Beattie, James K, McErlean, Christopher S. P
Format: Article
Language:English
Online Access:Get full text
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Summary:The conjugate addition of anilines onto unsaturated ketones, esters and N -acylpyrroles was investigated. Based on a recently proposed explanation for the phenomenon of on-water catalysis, operationally simple and mild reaction conditions for effecting these addition reactions have been developed. The success of these additions provides further support for the acid-catalysed nature of on-water chemistry. The conjugate addition of anilines to esters, enones and N -acryloylpyrroles has been accomplished using "on-water" reaction conditions.
ISSN:1359-7345
1364-548X
DOI:10.1039/c0cc02502j