Simple inexpensive boron electrophiles for direct arene borylationElectronic supplementary information (ESI) available: Experimental details for all compounds and, crystallographic information for 1. CCDC 837057. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c1cc14226g

Electrophilic direct borylation is facilitated, and arene substrate scope enhanced, by using electrophiles derived from inexpensive reagents; specifically an amine, BCl 3 and AlCl 3 . Electrophilic direct borylation is facilitated, and arene substrate scope enhanced, by using electrophiles derived f...

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Main Authors: Grosso, Alessandro Del, Helm, Matthew D, Solomon, Sophia A, Caras-Quintero, Dolores, Ingleson, Michael J
Format: Article
Language:English
Online Access:Get full text
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Summary:Electrophilic direct borylation is facilitated, and arene substrate scope enhanced, by using electrophiles derived from inexpensive reagents; specifically an amine, BCl 3 and AlCl 3 . Electrophilic direct borylation is facilitated, and arene substrate scope enhanced, by using electrophiles derived from an inexpensive amine, BCl 3 and AlCl 3 .
ISSN:1359-7345
1364-548X
DOI:10.1039/c1cc14226g