Polyoxometalate-directed assembly of water-soluble AgCl nanocubesElectronic supplementary information (ESI) available: Syntheses, electron microscopic, dynamic light-scattering and spectroscopic data, calculations, and crystallographic data. CCDC 838469. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c2cc16322e

Out-of-pocket association of Ag + to the tetradentate defect site of mono-vacant Keggin and Wells-Dawson polyoxometalate (POM) cluster-anions is used to direct the formation of water-soluble AgCl nanocubes. The tetradentate binding site of a mono-vacant Keggin polyoxometalate (POM) controls the reac...

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Main Authors: Neyman, Alevtina, Wang, Yifeng, Sharet, Shelly, Varsano, Neta, Botar, Bogdan, Kgerler, Paul, Meshi, Louisa, Weinstock, Ira A
Format: Article
Language:English
Online Access:Get full text
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Summary:Out-of-pocket association of Ag + to the tetradentate defect site of mono-vacant Keggin and Wells-Dawson polyoxometalate (POM) cluster-anions is used to direct the formation of water-soluble AgCl nanocubes. The tetradentate binding site of a mono-vacant Keggin polyoxometalate (POM) controls the reaction of Ag + with chloride in water, leading to highly-uniform POM-protected AgCl nanocubes.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc16322e