Chirality induction in metal-induced achiral polythiophene aggregates assisted by optically active amines and polythiopheneThis article is part of the ChemComm Chirality' web themed issue.Electronic supplementary information (ESI) available: Experimental details. See DOI: 10.1039/c2cc17940g

A regioregular achiral polythiophene bearing oxazoline pendant groups formed a unique optically active metal-induced supramolecular aggregate upon complexation with chiral amines or in the presence of a chiral polythiophene in a good solvent for the polymers, thus showing an induced circular dichroi...

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Main Authors: Goto, Hidetoshi, Yokochi, Yuko, Yashima, Eiji
Format: Article
Language:English
Online Access:Get full text
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Summary:A regioregular achiral polythiophene bearing oxazoline pendant groups formed a unique optically active metal-induced supramolecular aggregate upon complexation with chiral amines or in the presence of a chiral polythiophene in a good solvent for the polymers, thus showing an induced circular dichroism. An achiral polythiophene formed a unique optically active metal-induced supramolecular aggregate upon complexation with chiral amines or in the presence of a chiral polythiophene in a good solvent for the polymers, thus showing an induced circular dichroism.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc17940g