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Tricationic analogues of boroxines and polyborate anionsThis article is part of the ChemComm 'Frontiers in Molecular Main Group Chemistry' web themed issue.Electronic supplementary information (ESI) available: Experimental and computational details and crystallographic information. CCDC 876412-876415. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c2cc32605a
Addition of E 2 O (E = Me 3 Si or H) to [(pyridyl)BX 2 ][AlX 4 ] (X = Cl or Br) and subsequent heating produced the unprecedented trications [(2,6-lutidine) 4 B 5 O 6 ] 3+ and [(pyridine) 4 B 3 O 3 ] 3+ . Addition of E 2 O (E = Me 3 Si or H) to [(pyridyl)BX 2 ][AlX 4 ] (X = Cl or Br) and subsequent...
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| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Online Access: | Get full text |
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| Summary: | Addition of E
2
O (E = Me
3
Si or H) to [(pyridyl)BX
2
][AlX
4
] (X = Cl or Br) and subsequent heating produced the unprecedented trications [(2,6-lutidine)
4
B
5
O
6
]
3+
and [(pyridine)
4
B
3
O
3
]
3+
.
Addition of E
2
O (E = Me
3
Si or H) to [(pyridyl)BX
2
][AlX
4
] (X = Cl or Br) and subsequent heating produced the unprecedented trications [(2,6-lutidine)
4
B
5
O
6
]
3+
and [(pyridine)
4
B
3
O
3
]
3+
. |
|---|---|
| ISSN: | 1359-7345 1364-548X |
| DOI: | 10.1039/c2cc32605a |