Dearomatizing conversion of pyrazines to 1,4-dihydropyrazine derivatives via transition-metal-free diboration, silaboration, and hydroborationElectronic supplementary information (ESI) available: Experimental details and characterization data of the products. See DOI: 10.1039/c2cc34086k

Pyrazines and substituted pyrazines undergo addition of boron reagents having B-B, Si-B, and H-B bonds under transition-metal-free conditions, leading to high-yield synthesis of N -borylated 1,4-dihydropyrazines and 1,2,3,4-tetrahydropyrazine. Pyrazine undergoes addition of boron reagents having B-B...

Full description

Saved in:
Bibliographic Details
Main Authors: Oshima, Kazuyuki, Ohmura, Toshimichi, Suginome, Michinori
Format: Article
Language:English
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Pyrazines and substituted pyrazines undergo addition of boron reagents having B-B, Si-B, and H-B bonds under transition-metal-free conditions, leading to high-yield synthesis of N -borylated 1,4-dihydropyrazines and 1,2,3,4-tetrahydropyrazine. Pyrazine undergoes addition of boron reagents having B-B, Si-B, and H-B bonds under transition-metal-free conditions.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc34086k