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Novel heptanuclear copper(i) iodide cluster with a pinwheel shapeElectronic supplementary information (ESI) available: Experimental procedures and spectroscopic data for ligand L, compounds 1 and 2, crystallographic data, additional figures, photographs, and TGA for compounds 1 and 2. CCDC 902378 and 902379 (1 and 2). For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c2ce26664d
From the reaction of CuI with an N,S-donor ligand ( L ) under different molar ratios, two discrete polynuclear copper( i ) iodide complexes, [Cu 2 I 2 L 2 ] ( 1 ) and [Cu 7 I 7 L 3 ] ( 2 ) were isolated and characterised. Complex 1 contains a rhomboid-type Cu 2 I 2 cluster, whilst complex 2 is the f...
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| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Online Access: | Get full text |
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| Summary: | From the reaction of CuI with an N,S-donor ligand (
L
) under different molar ratios, two discrete polynuclear copper(
i
) iodide complexes, [Cu
2
I
2
L
2
] (
1
) and [Cu
7
I
7
L
3
] (
2
) were isolated and characterised. Complex
1
contains a rhomboid-type Cu
2
I
2
cluster, whilst complex
2
is the first example showing a pinwheel-type Cu
7
I
7
cluster.
From the reaction of CuI with a ligand (
L
) under different molar ratios, two discrete polynuclear copper(
i
) iodide complexes, [Cu
2
I
2
L
2
] (
1
) and [Cu
7
I
7
L
3
] (
2
) were isolated and characterised. In
2
, a pinwheel-type structure is the first example amongst copper halide clusters. |
|---|---|
| ISSN: | 1466-8033 |
| DOI: | 10.1039/c2ce26664d |