Vanadium-catalyzed enantioselective Friedel-Crafts-type reactionsElectronic supplementary information (ESI) available: Experimental procedures and analytical data. See DOI: 10.1039/c2dt32202a

Vanadium-mediated enantioselective Friedel-Crafts (FC)-type reactions were established using the dinuclear vanadium complex ( R a , S , S )- 1a . The vanadium complex promoted the FC-type reaction of imines with 2-naphthols or indoles to give corresponding adducts with high enantioselectivities. Fir...

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Main Authors: Takizawa, Shinobu, Arteaga, Fernando Arteaga, Yoshida, Yasushi, Kodera, Junpei, Nagata, Yoshihiro, Sasai, Hiroaki
Format: Article
Language:English
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Summary:Vanadium-mediated enantioselective Friedel-Crafts (FC)-type reactions were established using the dinuclear vanadium complex ( R a , S , S )- 1a . The vanadium complex promoted the FC-type reaction of imines with 2-naphthols or indoles to give corresponding adducts with high enantioselectivities. First vanadium-mediated enantioselective Friedel-Crafts (FC)-type reactions were established using the dinuclear vanadium complex.
ISSN:1477-9226
1477-9234
DOI:10.1039/c2dt32202a