Nickel phosphate molecular sieves VSB-5 as heterogeneous catalysts for synthesis of monosaccharides from formaldehyde and dihydroxyacetone

Condensation of dihydroxyacetone with formaldehyde was found to be effectively catalyzed by nickel phosphate molecular sieves (VSB-5 and Fe-VSB-5) in neutral aqueous medium. In the presence of VSB-5 the main products are erythrulose and 3-pentulose, while Fe-VSB-5 favours the formation of only eryth...

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Bibliographic Details
Published in:New journal of chemistry 2012, Vol.36 (11), p.221-224
Main Authors: Delidovich, Irina V, Timofeeva, Maria N, Orlov, Alexander Yu, Panchenko, Valentina N, Hasan, Zubair, Jhung, Sung Hwa, Taran, Oxana P, Parmon, Valentin N
Format: Article
Language:English
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Summary:Condensation of dihydroxyacetone with formaldehyde was found to be effectively catalyzed by nickel phosphate molecular sieves (VSB-5 and Fe-VSB-5) in neutral aqueous medium. In the presence of VSB-5 the main products are erythrulose and 3-pentulose, while Fe-VSB-5 favours the formation of only erythrulose. Condensation of dihydroxyacetone with formaldehyde was found to be effectively catalyzed by nickel phosphate molecular sieves (VSB-5 and Fe-VSB-5) in neutral aqueous medium.
ISSN:1144-0546
1369-9261
DOI:10.1039/c2nj40363c