Picture of a chelate in exchange: the crystal structure of NaHoDOTMA, a 'semi'-hydrated chelateElectronic supplementary information (ESI) available: 1H NMR spectra of HoDOTA and HoDOTMA; crystallographic parameters, refinement details, and images. CCDC 920762. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c3cc38814j

Crystallography generally only provides static structural information. This can render it an ineffective technique for probing dynamic solution state processes. A crystal of HoDOTMA affords unique structures that effectively represent that of a lanthanide tetra-acetate chelate mid-way through the wa...

Full description

Saved in:
Bibliographic Details
Main Authors: Payne, Katherine M, Valente, Edward J, Aime, Silvio, Botta, Mauro, Woods, Mark
Format: Article
Language:English
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Crystallography generally only provides static structural information. This can render it an ineffective technique for probing dynamic solution state processes. A crystal of HoDOTMA affords unique structures that effectively represent that of a lanthanide tetra-acetate chelate mid-way through the water exchange process. The crystal structure of NaHoDOTMA affords a picture of a chelate midway through the dissociative exchange process and insight into its solution state coordination chemistry.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc38814j