Functionalization of organic semiconductor crystals via the Diels-Alder reactionElectronic supplementary information (ESI) available: Procedures for substrate preparation/single crystal growth; sample reaction conditions; XPS data for a standard tetracene adduct and reacted rubrene crystals; crystal mass spectrometry data; general synthetic experimental details for standard adducts; and 1H, 13C NMR, and IR characterization spectra. See DOI: 10.1039/c3cc40866c

A surface adlayer is generated on organic single crystals (tetracene and rubrene) using the site specific Diels-Alder reaction and a series of vapor phase dienophiles. X-ray photoelectron spectroscopy (XPS) confirms adsorption on the surfaces of tetracene and rubrene and mass spectrometry demonstrat...

Full description

Saved in:
Bibliographic Details
Main Authors: Qualizza, Brittni A, Prasad, Srividya, Chiarelli, M. Paul, Ciszek, Jacob W
Format: Article
Language:English
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:A surface adlayer is generated on organic single crystals (tetracene and rubrene) using the site specific Diels-Alder reaction and a series of vapor phase dienophiles. X-ray photoelectron spectroscopy (XPS) confirms adsorption on the surfaces of tetracene and rubrene and mass spectrometry demonstrates the reaction's applicability to a range of dienophiles. The surface of single crystal organic semiconductors, tetracene and rubrene, reacted specifically, and with tolerance of various functional groups.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc40866c