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Titanium carbide@polypyrrole core-shell nanoparticles prepared by controlled heterogeneous nucleation for rechargeable batteriesElectronic supplementary information (ESI) available: XPS data of TiC and schematics of TiC-PPy interaction; experimental; electrochemical impedance spectroscopy analysis. See DOI: 10.1039/c3cc43406k

A unique nanostructure consisting of a TiC nanoparticle core and a conformal polypyrrole shell doped with p -toluene sulfonate has been synthesized by a controlled heterogeneous nucleation process. As an electrode material in a Li-ion containing organic electrolyte, the nanocomposite exhibits remark...

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Bibliographic Details
Main Authors: Weng, Yu-Ting, Wu, Nae-Lih
Format: Article
Language:English
Online Access:Get full text
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Summary:A unique nanostructure consisting of a TiC nanoparticle core and a conformal polypyrrole shell doped with p -toluene sulfonate has been synthesized by a controlled heterogeneous nucleation process. As an electrode material in a Li-ion containing organic electrolyte, the nanocomposite exhibits remarkable high-rate (up to 400 C-rate) charge-discharge capability and cycling stability even at 50 °C. TiC@PPy( p TS) core-shell nanoparticles are synthesized by controlled heterogeneous nucleation and exhibit remarkable high-rate performance for rechargeable batteries.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc43406k