Pd-Catalyzed stereospecific allyl-aryl coupling of allylic alcohols with arylboronic acidsElectronic supplementary information (ESI) available. See DOI: 10.1039/c3cc45053h

An efficient method for Pd-catalyzed stereospecific allyl-aryl coupling of allylic alcohols with arylboronic acids has been described. The reactions proceeded smoothly in the presence of Pd 2 (dba) 3 ·CHCl 3 and racemic BINAP under mild and neutral conditions, affording allyl-aryl coupling products...

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Main Authors: Ye, Jiang, Zhao, Jingming, Xu, Jing, Mao, Yuxue, Zhang, Yong Jian
Format: Article
Language:English
Online Access:Get full text
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Summary:An efficient method for Pd-catalyzed stereospecific allyl-aryl coupling of allylic alcohols with arylboronic acids has been described. The reactions proceeded smoothly in the presence of Pd 2 (dba) 3 ·CHCl 3 and racemic BINAP under mild and neutral conditions, affording allyl-aryl coupling products in moderate to high yields with excellent stereospecificities. An efficient method for Pd-catalyzed stereospecific allyl-aryl coupling of allylic alcohols with arylboronic acids has been described. The reactions proceeded smoothly in the presence of Pd 2 (dba) 3 ·CHCl 3 and racemic BINAP under mild and neutral conditions, affording allyl-aryl coupling products in moderate to high yields with excellent enantiospecificities.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc45053h