Above-room-temperature ferroelastic phase transition in a perovskite-like compound [N(CH3)4][Cd(N3)3]Electronic supplementary information (ESI) available: Experimental details and characterizations. CCDC 970021-970023. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c3cc48581a

A new perovskite-like compound [N(CH 3 ) 4 ][Cd(N 3 ) 3 ] is reported here, which undergoes a series of reversible phase transitions including an above-room-temperature ferroelastic phase transition. An order-disorder mechanism is found in these structural transitions owing to the sway of the rod-li...

Full description

Saved in:
Bibliographic Details
Main Authors: Du, Zi-Yi, Zhao, Ying-Ping, Zhang, Wei-Xiong, Zhou, Hao-Long, He, Chun-Ting, Xue, Wei, Wang, Bao-Ying, Chen, Xiao-Ming
Format: Article
Language:English
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:A new perovskite-like compound [N(CH 3 ) 4 ][Cd(N 3 ) 3 ] is reported here, which undergoes a series of reversible phase transitions including an above-room-temperature ferroelastic phase transition. An order-disorder mechanism is found in these structural transitions owing to the sway of the rod-like N 3 − bridges as well as the rotation of the tetrahedron-like [N(CH 3 ) 4 ] + guests. A perovskite-like compound [N(CH 3 ) 4 ][Cd(N 3 ) 3 ] undergoes a series of reversible phase transitions including a ferroelastic type. An order-disorder mechanism is found in these structural transitions.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc48581a