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Hydrothermal route to metastable phase FeVO ultrathin nanosheets with exposed {010} facets: synthesis, photocatalysis and gas-sensing

In this paper, pure metastable phase iron vanadate (FeVO 4 -II) ultrathin nanosheets (50 nm in thickness) with exposed {010} facets were obtained by a mild hydrothermal process, without the use of any template or organic surfactant. The photocatalytic rate of the FeVO 4 -II {010} facets was measured...

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Bibliographic Details
Published in:CrystEngComm 2013-12, Vol.16 (2), p.27-276
Main Authors: Zhao, Yi, Yao, Kai, Cai, Qian, Shi, Zhijie, Sheng, Minqi, Lin, Haiyang, Shao, Mingwang
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Summary:In this paper, pure metastable phase iron vanadate (FeVO 4 -II) ultrathin nanosheets (50 nm in thickness) with exposed {010} facets were obtained by a mild hydrothermal process, without the use of any template or organic surfactant. The photocatalytic rate of the FeVO 4 -II {010} facets was measured taking advantage of their unique morphology. Furthermore, the FeVO 4 -II catalyst could be easily separated and reused, simply by applying an external magnetic field. In addition, with their n-type semiconductor structure, FeVO 4 ultrathin nanosheets exhibited gas-sensing for an ethanol trace. Metastable phase iron vanadate (FeVO 4 -II) ultrathin nanosheets with exposed {010} facets were obtained by a hydrothermal process. Their photocatalytic rate and gas-sensing of trace ethanol were measured.
ISSN:1466-8033
DOI:10.1039/c3ce41692e