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One-dimension TiO2 nanostructures: oriented attachment and application in dye-sensitized solar cellElectronic supplementary information (ESI) available: Additional experimental results are available, including the time dependent experiment, hydroxyl group dependent experiment, morphology dependent experiment, and characterization of FTIR and XPS, I-V curves and efficiency parameters of DSSCs. See DOI: 10.1039/c3ce41867g

Oriented attachment, as aggregation based crystallization, is one of the most promising approaches in designing novel nanostructures. A two-step solvothermal method is reported in this work to synthesize TiO 2 nanochains with one-dimensional single-crystalline nature, which is formed by oriented att...

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Bibliographic Details
Main Authors: Chen, Chao, Wang, Jia, Ren, Zhimin, Qian, Guodong, Wang, Zhiyu
Format: Article
Language:English
Online Access:Get full text
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Summary:Oriented attachment, as aggregation based crystallization, is one of the most promising approaches in designing novel nanostructures. A two-step solvothermal method is reported in this work to synthesize TiO 2 nanochains with one-dimensional single-crystalline nature, which is formed by oriented attachment and with tunable length. We achieved selectively reducing the stereo-hindrance effect at (001) surfaces and making the processes of Ostwald ripening and oriented attachment asynchronous. By virtue of the 1D single crystalline nature, the conversion efficiency of dye-sensitized solar cell was improved. This approach opens the door for controllable oriented attachment, and it is meaningful for designing novel nanoarchitectures. TiO 2 nanochains with tunable length formed via oriented attachment and enhanced the conversion efficiency of DSSCs.
ISSN:1466-8033
DOI:10.1039/c3ce41867g