Direct carboxylation of allylic halides with carbon dioxide in the presence of indiumElectronic supplementary information (ESI) available: Experimental procedures, characterization data, and copies of 1H NMR and 13C NMR spectra. See DOI: 10.1039/c4cc00148f

A highly regioselective indium-mediated allylation of carbon dioxide starting from simple allylic halides (X = I, Br, Cl) has been developed. No transition metal catalyst is needed and an inert atmosphere is not necessary. The reaction tolerates a wide range of synthetically attractive functional gr...

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Main Authors: Miao, Bukeyan, Ma, Shengming
Format: Article
Language:English
Online Access:Get full text
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Summary:A highly regioselective indium-mediated allylation of carbon dioxide starting from simple allylic halides (X = I, Br, Cl) has been developed. No transition metal catalyst is needed and an inert atmosphere is not necessary. The reaction tolerates a wide range of synthetically attractive functional groups with a very high branched regioselectivity. A highly regioselective indium-mediated allylation of carbon dioxide starting from simple allylic halides (X = I, Br, Cl) has been developed.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc00148f