Direct observation of supported W bis-methylidene from supported W-methyl/methylidyne speciesElectronic supplementary information (ESI) available. See DOI: 10.1039/c4cc00286e

Extensive solid-state NMR analyses unambiguously determine the formation of silica supported W bis-methylidene methyl species by reaction of the corresponding methyl carbyne with trimethylphosphine or a cyclic olefin. Direct observation of supported W bis-methylidene from supported W methyl/methylid...

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Main Authors: Callens, E, Abou-Hamad, E, Riache, N, Basset, J. M
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creator Callens, E
Abou-Hamad, E
Riache, N
Basset, J. M
description Extensive solid-state NMR analyses unambiguously determine the formation of silica supported W bis-methylidene methyl species by reaction of the corresponding methyl carbyne with trimethylphosphine or a cyclic olefin. Direct observation of supported W bis-methylidene from supported W methyl/methylidyne species.
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title Direct observation of supported W bis-methylidene from supported W-methyl/methylidyne speciesElectronic supplementary information (ESI) available. See DOI: 10.1039/c4cc00286e
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