Extended and functionalized porous iron(iii) tri- or dicarboxylates with MIL-100/101 topologiesThis paper is dedicated to Prof. G. Férey for his exceptional and constant encouragement.Electronic supplementary information (ESI) available: Synthesis details, XRD, IR, TGA, N2 isotherms, solvent stability and computing simulation. See DOI: 10.1039/c4cc02175d

A series of nanometric isoreticular and/or functionalized analogues of the mesoporous environmentally-friendly iron( iii ) polycarboxylates MIL-100/101 have been successfully synthesized. Their exceptional pore size, of up to 68 Å, together with their relatively good stability in solvents, makes the...

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Main Authors: Horcajada, Patricia, Chevreau, Hubert, Heurtaux, Daniela, Benyettou, Farah, Salles, Fabrice, Devic, Thomas, Garcia-Marquez, Alfonso, Yu, Cihang, Lavrard, Hubert, Dutson, Claire L, Magnier, Emmanuel, Maurin, Guillaume, Elkaïm, Erik, Serre, Christian
Format: Article
Language:English
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Summary:A series of nanometric isoreticular and/or functionalized analogues of the mesoporous environmentally-friendly iron( iii ) polycarboxylates MIL-100/101 have been successfully synthesized. Their exceptional pore size, of up to 68 Å, together with their relatively good stability in solvents, makes them promising candidates for heterogeneous catalysis or inclusion of large molecules, among others. Nanometric isoreticular and functionalized mesoporous iron( iii ) polycarboxylates MIL-100/101 have been synthesized with exceptional porosities and good solvent-stability.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc02175d