Visible-light-enhanced Suzuki-Miyaura coupling reaction by cooperative photocatalysis with an Ru-Pd bimetallic complexElectronic supplementary information (ESI) available: Experimental procedures and XAFS. See DOI: 10.1039/c4cc03682d

A photo-assisted Suzuki-Miyaura coupling reaction has been realized by a molecule Pd( ii ) complex containing a Ru( ii )-polypyridyl derivative as a visible light photosensitizing unit, where an electron transfer from excited Ru species to Pd forms an active electron rich Pd(0) and facilitates the o...

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Bibliographic Details
Main Authors: Mori, Kohsuke, Kawashima, Masayoshi, Yamashita, Hiromi
Format: Article
Language:English
Online Access:Get full text
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Summary:A photo-assisted Suzuki-Miyaura coupling reaction has been realized by a molecule Pd( ii ) complex containing a Ru( ii )-polypyridyl derivative as a visible light photosensitizing unit, where an electron transfer from excited Ru species to Pd forms an active electron rich Pd(0) and facilitates the oxidative addition step with aryl halides. A photo-assisted Suzuki-Miyaura coupling reaction has been realized by a molecule Pd( ii ) complex containing a Ru( ii )-polypyridyl derivative as a visible light photosensitizing unit.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc03682d