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A highly active PtCu3 intermetallic core-shell, multilayered Pt-skin, carbon embedded electrocatalyst produced by a scale-up sol-gel synthesis

We present a novel, scaled-up sol-gel synthesis which enables one to produce 20 g batches of highly active and stable carbon supported PtCu 3 nanoparticles as cathode materials for low temperature fuel cell application. We confirm the presence of an ordered intermetallic phase underneath a multilaye...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2014-11, Vol.5 (86), p.13124-13126
Main Authors: Bele, M, Jovanovi, P, Pavliši, A, Jozinovi, B, Zorko, M, Re nik, A, Chernyshova, E, Ho evar, S, Hodnik, N, Gaberš ek, M
Format: Article
Language:English
Online Access:Get full text
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Summary:We present a novel, scaled-up sol-gel synthesis which enables one to produce 20 g batches of highly active and stable carbon supported PtCu 3 nanoparticles as cathode materials for low temperature fuel cell application. We confirm the presence of an ordered intermetallic phase underneath a multilayered Pt-skin together with firm embedment of nanoparticles in the carbon matrix. We present a novel, scaled-up sol-gel synthesis which enables one to produce 20 g batches of highly active and stable carbon supported PtCu 3 nanoparticles as cathode materials for low temperature fuel cell application.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc05637j