Co@NH2-MIL-125(Ti): cobaloxime-derived metal-organic framework-based composite for light-driven H2 productionElectronic supplementary information (ESI) available: Experimental methods, spectroscopic and analytical data on catalyst and assembly characterization, photocatalysis and recycling results. This material is available free of charge via the internet at See DOI: 10.1039/c4ee02853h

We present a synthetic strategy for the efficient encapsulation of a derivative of a well-defined cobaloxime proton reduction catalyst within a photoresponsive metal-organic framework ( NH 2 -MIL-125(Ti) ). The resulting hybrid system Co@MOF is demonstrated to be a robust heterogeneous composite mat...

Full description

Saved in:
Bibliographic Details
Main Authors: Nasalevich, M. A, Becker, R, Ramos-Fernandez, E. V, Castellanos, S, Veber, S. L, Fedin, M. V, Kapteijn, F, Reek, J. N. H, van der Vlugt, J. I, Gascon, J
Format: Article
Language:English
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:We present a synthetic strategy for the efficient encapsulation of a derivative of a well-defined cobaloxime proton reduction catalyst within a photoresponsive metal-organic framework ( NH 2 -MIL-125(Ti) ). The resulting hybrid system Co@MOF is demonstrated to be a robust heterogeneous composite material. Furthermore, Co@MOF is an efficient and fully recyclable noble metal-free catalyst system for light-driven hydrogen evolution from water under visible light illumination. Encapsulation of cobalt catalyst within the pores of a photoresponsive MOF results in very efficient and fully recyclable noble metal-free photocatalyst for hydrogen evolution from water under visible light illumination.
ISSN:1754-5692
1754-5706
DOI:10.1039/c4ee02853h