Organocatalysis for new chiral fullerene-based materialsElectronic Supplementary Information (ESI) available. See DOI: 10.1039/c4fd00065j

The cycloaddition reaction of 3-alkynoates to fullerenes has been studied under different experimental conditions and phosphines in the presence of a base which is responsible for the previous isomerization to the corresponding allenoate. The versatility of this reaction allows chiral fullerenes to...

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Main Authors: Girón, Rosa M, Reboredo, Silvia, Marco-Martínez, Juan, Filippone, Salvatore, Martín, Nazario
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Reboredo, Silvia
Marco-Martínez, Juan
Filippone, Salvatore
Martín, Nazario
description The cycloaddition reaction of 3-alkynoates to fullerenes has been studied under different experimental conditions and phosphines in the presence of a base which is responsible for the previous isomerization to the corresponding allenoate. The versatility of this reaction allows chiral fullerenes to be obtained at will, thus opening up a new avenue in the use of enantiomerically pure carbon nanostructures in materials science.
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title Organocatalysis for new chiral fullerene-based materialsElectronic Supplementary Information (ESI) available. See DOI: 10.1039/c4fd00065j
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