Metal-free aerobic oxidative C-N bond cleavage of tertiary amines for the synthesis of N-heterocycles with high atom efficiencyElectronic supplementary information (ESI) available. See DOI: 10.1039/c4ob00578c

An efficient metal-free aerobic oxidative C-N bond cleavage of tertiary amines has been developed to construct N-heterocycles using molecular oxygen as the sole oxidant with high atom efficiency, in which all of the three alkyl groups in tertiary amines can be utilized and transformed into N-heteroc...

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Main Authors: Chen, Xiuling, Chen, Tieqiao, Zhou, Yongbo, Han, Daoqing, Han, Li-Biao, Yin, Shuang-Feng
Format: Article
Language:English
Online Access:Get full text
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Summary:An efficient metal-free aerobic oxidative C-N bond cleavage of tertiary amines has been developed to construct N-heterocycles using molecular oxygen as the sole oxidant with high atom efficiency, in which all of the three alkyl groups in tertiary amines can be utilized and transformed into N-heterocycles. An efficient metal-free aerobic C-N bond cleavage of tertiary amines has been developed to construct N-heterocycles using molecular oxygen as the sole oxidant with high atom efficiency. All of the three alkyl groups in tertiary amines can be utilized and transformed into N-heterocycles.
ISSN:1477-0520
1477-0539
DOI:10.1039/c4ob00578c