enantio-Enriched CPL-active helicene-bipyridine-rhenium complexesElectronic supplementary information (ESI) available: Synthetic, spectroscopic and computational details. CCDC 857156, 939180 and 942143. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5cc00453e

The incorporation of a rhenium atom within an extended helical π-conjugated bi-pyridine system impacts the chiroptical and photophysical properties of the resulting neutral or cationic complexes, leading to the first examples of rhenium-based phosphors that exhibit circularly polarized luminescence....

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Main Authors: Saleh, Nidal, Srebro, Monika, Reynaldo, Thibault, Vanthuyne, Nicolas, Toupet, Loïc, Chang, Victoria Y, Muller, Gilles, Williams, J. A. Gareth, Roussel, Christian, Autschbach, Jochen, Crassous, Jeanne
Format: Article
Language:English
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Summary:The incorporation of a rhenium atom within an extended helical π-conjugated bi-pyridine system impacts the chiroptical and photophysical properties of the resulting neutral or cationic complexes, leading to the first examples of rhenium-based phosphors that exhibit circularly polarized luminescence. Incorporation of a rhenium atom within an extended helical π-conjugated bi-pyridine system leads to the first examples of rhenium-based phosphors that exhibit circularly polarized luminescence.
ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc00453e