Visible light promoted carbodifluoroalkylation of allylic alcohols via concomitant 1,2-aryl migrationElectronic supplementary information (ESI) available. See DOI: 10.1039/c5cc01189b

A novel visible light promoted carbodifluoroalkylation of allylic alcohols is disclosed. A series of difluoro 1,5-dicarbonyl compounds were obtained through a tandem radical addition and 1,2-aryl migration process. Mechanistic analysis indicated that the 1,2-aryl rearrangement proceeded via a radica...

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Bibliographic Details
Main Authors: Xu, Pan, Hu, Kaidong, Gu, Zhangxi, Cheng, Yixiang, Zhu, Chengjian
Format: Article
Language:English
Online Access:Get full text
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Summary:A novel visible light promoted carbodifluoroalkylation of allylic alcohols is disclosed. A series of difluoro 1,5-dicarbonyl compounds were obtained through a tandem radical addition and 1,2-aryl migration process. Mechanistic analysis indicated that the 1,2-aryl rearrangement proceeded via a radical intermediate. A novel visible light promoted carbodifluoroalkylation of allylic alcohols is disclosed.
ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc01189b