Copper(i)-photocatalyzed trifluoromethylation of alkenesElectronic supplementary information (ESI) available: Synthesis and characterization of compounds 4, 5a-e, 6a-b; ES-MS, UV-vis and EPR spectra; cyclic voltammogram of 2. See DOI: 10.1039/c5cc01923k

Using the photoreducible Cu II precatalyst 2, trifluoromethylation reactions of alkenes are conducted effectively at low copper loading (0.1-0.5 mol%) on exposing the reaction mixture to sunlight/ambient light. Using the photoreducible Cu II precatalyst 2 , trifluoromethylation of terminal alkenes c...

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Main Authors: Beniazza, R, Molton, F, Duboc, C, Tron, A, McClenaghan, N. D, Lastécouères, D, Vincent, J.-M
Format: Article
Language:English
Online Access:Get full text
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Summary:Using the photoreducible Cu II precatalyst 2, trifluoromethylation reactions of alkenes are conducted effectively at low copper loading (0.1-0.5 mol%) on exposing the reaction mixture to sunlight/ambient light. Using the photoreducible Cu II precatalyst 2 , trifluoromethylation of terminal alkenes can be conducted at low copper loading on exposing the reaction mixture to sunlight/ambient light.
ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc01923k