Azo-functionalized microporous organic polymers: synthesis and applications in CO2 capture and conversionElectronic supplementary information (ESI) available: For experimental details and spectral data. See DOI: 10.1039/c5cc03151f

Azo-functionalized MOPs (Azo-MOPs) were synthesized via oxidative polymerization of aromatic amines catalyzed by t -BuOCl/NaI (25 °C, 1 h, yield: >95%), which displayed an excellent coordinating ability with a Ru complex. The resulting Ru-coordinated Azo-MOPs displayed high CO 2 capacity and high...

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Main Authors: Yang, Zhenzhen, Zhang, Hongye, Yu, Bo, Zhao, Yanfei, Ma, Zhishuang, Ji, Guipeng, Han, Buxing, Liu, Zhimin
Format: Article
Language:English
Online Access:Get full text
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Summary:Azo-functionalized MOPs (Azo-MOPs) were synthesized via oxidative polymerization of aromatic amines catalyzed by t -BuOCl/NaI (25 °C, 1 h, yield: >95%), which displayed an excellent coordinating ability with a Ru complex. The resulting Ru-coordinated Azo-MOPs displayed high CO 2 capacity and high performances for catalyzing the methylation of amines with CO 2 under low pressure (0.5 MPa). Azo-functionalized microporous organic polymers were synthesized under mild conditions (25 °C, 1 h, yield: >95%), and displayed high CO 2 capacity and high performances for catalyzing the methylation of amines with CO 2 under low pressure (0.5 MPa).
ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc03151f