Organocatalysts with carbon-centered activity for CO2 reduction with boranesElectronic supplementary information (ESI) available: Experimental details. CCDC 1400031. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5cc04337a

We report two organocatalysts for CO 2 hydroboration to methylborylethers, which upon hydrolysis can produce methanol. These organocatalysts feature carbon-centered reversible CO 2 binding, broad borane scopes, and high catalytic activities. We report two C/H/N-only organocatalysts with carbon-cente...

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Bibliographic Details
Main Authors: Yang, Yanxin, Xu, Maotong, Song, Datong
Format: Article
Language:English
Online Access:Get full text
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Summary:We report two organocatalysts for CO 2 hydroboration to methylborylethers, which upon hydrolysis can produce methanol. These organocatalysts feature carbon-centered reversible CO 2 binding, broad borane scopes, and high catalytic activities. We report two C/H/N-only organocatalysts with carbon-centered reactivity for CO 2 reduction to methanol.
ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc04337a