Quantum-CORMs: quantum dot sensitized CO releasing moleculesElectronic supplementary information (ESI) available: Synthetic and analytical details, UV-Vis spectra of Mn(i) complexes and Mn-QD conjugates, and calculation details. See DOI: 10.1039/c5dt01681a

The synthesis and photodecomposition behaviour of a family of CO releasing molecules (CORMs) based on [Mn(CO) 3 bpy] derivatives connected to a semiconductor Quantum Dot (QD) sensitizer is described here. Compared to the non-sensitized complexes, such systems show a 2 to 6-fold increase of the photo...

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Bibliographic Details
Main Authors: Ruggi, A, Zobi, F
Format: Article
Language:English
Online Access:Get full text
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Summary:The synthesis and photodecomposition behaviour of a family of CO releasing molecules (CORMs) based on [Mn(CO) 3 bpy] derivatives connected to a semiconductor Quantum Dot (QD) sensitizer is described here. Compared to the non-sensitized complexes, such systems show a 2 to 6-fold increase of the photodecomposition rate upon irradiation with visible light. Quantum dot sensitized photoactive CORMs show a 2 to 6-fold increase of the photodecomposition rate upon irradiation with visible light.
ISSN:1477-9226
1477-9234
DOI:10.1039/c5dt01681a