Iron-catalyzed cross coupling of P-H/C-O bonds: efficient synthesis of α-alkoxyphosphorus compounds

An efficient P-C bond-formation through iron-catalyzed cross coupling of P-H/C-O bonds is developed for the first time. This reaction proceeds efficiently to produce the corresponding valuable α-alkoxyphosphorus compounds under mild conditions with a wide generality. An efficient P-C bond-formation...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2016-01, Vol.45 (5), p.1877-188
Main Authors: Li, Xue, Chen, Tieqiao, Saga, Yuta, Han, Li-Biao
Format: Article
Language:English
Subjects:
Bonding
Cross coupling
Synthesis
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Summary:An efficient P-C bond-formation through iron-catalyzed cross coupling of P-H/C-O bonds is developed for the first time. This reaction proceeds efficiently to produce the corresponding valuable α-alkoxyphosphorus compounds under mild conditions with a wide generality. An efficient P-C bond-formation through iron-catalyzed cross coupling of P-H/C-O bonds is developed for the first time. This reaction proceeds efficiently to produce the corresponding valuable α-alkoxyphosphorus compounds under mild conditions with a wide generality.
ISSN:1477-9226
1477-9234
DOI:10.1039/c5dt02454d