Copper-catalyzed electrophilic amination using -methoxyamines

Copper-catalyzed electrophilic amination of a triarylboroxin using an N -methoxyamine to give quick access to a variety of anilines was reported. The reaction was especially useful for syntheses of functionalized anilines when combined with our previously reported nucleophilic addition to N -methoxy...

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Published in:Organic & biomolecular chemistry 2016-06, Vol.14 (24), p.5486-5489
Main Authors: Fukami, Yutaro, Wada, Takamasa, Meguro, Tatsuhiko, Chida, Noritaka, Sato, Takaaki
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container_title Organic & biomolecular chemistry
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creator Fukami, Yutaro
Wada, Takamasa
Meguro, Tatsuhiko
Chida, Noritaka
Sato, Takaaki
description Copper-catalyzed electrophilic amination of a triarylboroxin using an N -methoxyamine to give quick access to a variety of anilines was reported. The reaction was especially useful for syntheses of functionalized anilines when combined with our previously reported nucleophilic addition to N -methoxyamides. Copper-catalyzed electrophilic amination using functionalized N -methoxyamines, prepared by nucleophilic addition to N -methoxyamides, is reported.
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title Copper-catalyzed electrophilic amination using -methoxyamines
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