Nanostructured oxyhydroxide niobium (NbOOH) as UV radiation protector for polypropylene

• Published in: RSC advances 2016-01, Vol.6 (6), p.54-548
• Main Authors: Souza, Samara D, Pereira, Iaci M, Rodrigues, Ana Pacheli H, Oliveira, Luiz C. A, Boaventura, Tulio P, Souza, Alexandre R, Oréfice, Rodrigo L, Patricio, Patrícia S. O
• Format: Article
• Language: English
• Subjects: Degradation; Hydrogen peroxide; Microscopy; Nanoparticles; Niobium; Polypropylenes; Synchrotron radiation; Ultraviolet radiation
• ISSN: 2046-2069; 2046-2069
• DOI: 10.1039/c5ra08514d

In this study a novel approach for improving the photo-stabilization of polymers by incorporation of nanoparticles of a new niobium compound is reported. For the first time, this approach uses the electronic properties of niobium oxyhydroxide to absorb UV light efficiently to avoid the decomposition of the polymers. The innovative results of this work consist of preparing nanoparticles of niobium oxyhydroxide and its modification by treatment with hydrogen peroxide to alter their ability to absorb radiation and act as a photo-stabilizer for preventing polypropylene degradation. Synchrotron radiation was employed: (i) to explore the niobium nanoparticle form and (ii) to investigate the macromolecular structure of neat PP and PP/Nb compounds before and after degradation. The results from this research study using FTIR-ATR, DSC and microscopies, as TEM, SEM and OM, indicate that the incorporation of niobium oxyhydroxide nanoparticles into the PP matrix provides stability against the action of ultraviolet radiation. In this study a novel approach for improving the photo-stabilization of polymers by incorporation of nanoparticles of a new niobium compound is reported.