Effect of iron-subgroup metal salts on polymer cord pyrolysis

For the first time, the effects of iron-subgroup metal chlorides on polymer cord conversion to liquid and gaseous pyrolysis products have been studied. The optimum parameters for pyrolysis were identified ( T = 450 °C, CoCl 2 2 wt%). The presence of aprotic acidic centers of the iron-subgroup metal...

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Bibliographic Details
Published in:RSC advances 2015-01, Vol.5 (7), p.5646-56469
Main Authors: Lugovoy, Yu. V, Chalov, K. V, Tkachenko, O. P, Sulman, E. M, Wärnå, J, Murzin, D. Yu
Format: Article
Language:English
Subjects:
Catalysis
Catalysts
Conversion
Liquids
Metal chlorides
Optimization
Pyrolysis
Rope
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Summary:For the first time, the effects of iron-subgroup metal chlorides on polymer cord conversion to liquid and gaseous pyrolysis products have been studied. The optimum parameters for pyrolysis were identified ( T = 450 °C, CoCl 2 2 wt%). The presence of aprotic acidic centers of the iron-subgroup metal chlorides on the polymer cord was confirmed by FTIR. The catalytic effect of iron-subgroup metal chlorides is predominantly attributed to the acidic properties of the catalysts used. For the first time, the effects of iron-subgroup metal chlorides on polymer cord conversion to liquid and gaseous pyrolysis products have been studied.
ISSN:2046-2069
2046-2069
DOI:10.1039/c5ra09656a