Local distortion energy and coarse-grained elasticity of the twist-bend nematic phaseElectronic supplementary information (ESI) available. See DOI: 10.1039/c5sm02018b

• Main Authors: Meyer, C, Dozov, I
• Format: Article
• ISSN: 1744-683X; 1744-6848
• DOI: 10.1039/c5sm02018b

The recently discovered twist-bend nematic phase of achiral bent-shaped molecules, N TB , has a doubly degenerate ground-state with a periodically modulated heliconical structure and unusual distortion elasticity, the theoretical description of which is still debated. We show that the N TB phase has the same macroscopic symmetry as another periodic mesophase, the chiral smectic-A, SmA*. Based on this N TB /SmA* analogy, we develop a coarse-grained elastic model for the N TB phase. Adopting one of the existing microscopic N TB elastic models, we calculate the coarse-grained elastic constants, coherence and penetration lengths in terms of a few Frank-like nematic elastic coefficients that can be measured in macroscopic experiments. The same coarse-grained approach, applied to different local elastic models, may provide an efficient experimental test of their validity. We show that the anisotropy of the N TB coarse-grained elasticity is opposite to that of the SmA*, leading probably to different configurations of some of the defects of the "layered" N TB structure. Moreover, we argue that the intrinsic chiral frustration of the N TB phase may be resolved by penetration of the twist field into the bulk through a network of screw dislocations of the N TB pseudo-layers, resulting in a twist-bend analogue of the twist grain boundary phase TGB A . We develop a coarse-grained model describing the macroscopic elasticity of the twist-bend nematic by analogy with the chiral smectic-A phase.