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Multi-responsive coordination polymers utilising metal-stabilised, dynamic covalent imine bonds

We report how the combination of dynamic covalent imine bonds and coordination bonds in a single polymer material not only imparts enhanced stability to the final polymer, but also allows the material to be sensitive to a range of stimuli, offering more fine-grained control over its properties. Inco...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (58), p.959-962
Main Authors: García, Fátima, Pelss, Janis, Zuilhof, Han, Smulders, Maarten M. J
Format: Article
Language:English
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Summary:We report how the combination of dynamic covalent imine bonds and coordination bonds in a single polymer material not only imparts enhanced stability to the final polymer, but also allows the material to be sensitive to a range of stimuli, offering more fine-grained control over its properties. Incorporation of dynamic imine bonds into coordination polymers yields stable polymers that are sensitive to a range of stimuli.
ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc00500d