Multi-responsive coordination polymers utilising metal-stabilised, dynamic covalent imine bonds

We report how the combination of dynamic covalent imine bonds and coordination bonds in a single polymer material not only imparts enhanced stability to the final polymer, but also allows the material to be sensitive to a range of stimuli, offering more fine-grained control over its properties. Inco...

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Published in:Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (58), p.959-962
Main Authors: García, Fátima, Pelss, Janis, Zuilhof, Han, Smulders, Maarten M. J
Format: Article
Language:English
Subjects:
Chemical bonds
Coordination polymers
Covalence
Dynamic mechanical properties
Dynamics
Imines
Laboratorium voor Organische chemie
Laboratory for Organic Chemistry
Organic Chemistry
Organische Chemie
Stability
Stimuli
VLAG
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description We report how the combination of dynamic covalent imine bonds and coordination bonds in a single polymer material not only imparts enhanced stability to the final polymer, but also allows the material to be sensitive to a range of stimuli, offering more fine-grained control over its properties. Incorporation of dynamic imine bonds into coordination polymers yields stable polymers that are sensitive to a range of stimuli.
doi_str_mv 10.1039/c6cc00500d
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source Royal Society of Chemistry
subjects Chemical bonds
Coordination polymers
Covalence
Dynamic mechanical properties
Dynamics
Imines
Laboratorium voor Organische chemie
Laboratory for Organic Chemistry
Organic Chemistry
Organische Chemie
Stability
Stimuli
VLAG
title Multi-responsive coordination polymers utilising metal-stabilised, dynamic covalent imine bonds
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