Visible-light-induced photocatalytic azotrifluoromethylation of alkenes with aryldiazonium salts and sodium triflinate

The efficient visible light photocatalytic azotrifluoromethylation of alkenes with aryldiazonium salts and sodium triflinate is described, which gave the corresponding trifluoromethylated azo compounds in generally good yields. The trifluoromethylated azo products can be easily transformed into usef...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (53), p.8275-8278
Main Authors: Yu, Xing-Long, Chen, Jia-Rong, Chen, Dong-Zhen, Xiao, Wen-Jing
Format: Article
Language:English
Subjects:
Alkenes
Azo
Azo compounds
Photocatalysis
Sodium
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Summary:The efficient visible light photocatalytic azotrifluoromethylation of alkenes with aryldiazonium salts and sodium triflinate is described, which gave the corresponding trifluoromethylated azo compounds in generally good yields. The trifluoromethylated azo products can be easily transformed into useful heterocycles and nitrogen-containing building blocks. Visible light photocatalytic azotrifluoromethylation of alkenes with aryldiazonium salts and sodium triflinate is described, which gave the trifluoromethylated azo compounds in good yields.
ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc03335k