Alkaline-earth phosphonate MOFs with reversible hydration-dependent fluorescenceElectronic supplementary information (ESI) available: Supporting TGA, SEM, gas sorption, fluorescence emission, PXRD, and diffuse reflectance data, as well as synthetic and NMR data are provided. CCDC 1497928. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6cc06490f

A new rigid tritopic phosphonic ligand, 2,4,6-tris(4-phosphonophenyl)pyridine ( H 6 L ), was synthesized and used to assemble isostructural barium ( 1 ) and strontium ( 2 ) phosphonate metal organic frameworks that exhibit fully reversible and selective water-dependent fluorescence red-shift at room...

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Main Authors: Fard, Z. H, Kalinovskyy, Y, Spasyuk, D. M, Blight, B. A, Shimizu, G. K. H
Format: Article
Language:English
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Summary:A new rigid tritopic phosphonic ligand, 2,4,6-tris(4-phosphonophenyl)pyridine ( H 6 L ), was synthesized and used to assemble isostructural barium ( 1 ) and strontium ( 2 ) phosphonate metal organic frameworks that exhibit fully reversible and selective water-dependent fluorescence red-shift at room temperature. A new rigid tritopic phosphonic ligand, 2,4,6-tris(4-phosphonophenyl)pyridine ( H 6 L ), was synthesized and used to assemble isostructural barium ( 1 ) and strontium ( 2 ) phosphonate metal organic frameworks that exhibit fully reversible and selective water-dependent fluorescence red-shift at room temperature.
ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc06490f