A perylene bisimide network for high-performance n-type electrochromismElectronic supplementary information (ESI) available: Experimental details, synthesis, structure determination, optical properties, and electrochemical characterization. See DOI: 10.1039/c6cc07962h

A micro-porous network thin film of core-tetrachlorinated perylene bisimide (PBI) was deposited by electrochemical polymerization, which showed reversible n-doping/dedoping processes at rather low potentials, accompanied by color changes from an orange red (neutral) state to a transparent (radical a...

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Main Authors: Ma, Weitao, Qin, Leiqiang, Gao, Yu, Zhang, Wenqiang, Xie, Zengqi, Yang, Bing, Liu, Linlin, Ma, Yuguang
Format: Article
Language:English
Online Access:Get full text
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Summary:A micro-porous network thin film of core-tetrachlorinated perylene bisimide (PBI) was deposited by electrochemical polymerization, which showed reversible n-doping/dedoping processes at rather low potentials, accompanied by color changes from an orange red (neutral) state to a transparent (radical anion) state and further to an aquamarine (dianion) state. The film possesses preferable coloration efficiency and cycling stability (>10 000 cycles). A micro-porous network thin film of core-tetrachlorinated perylene bisimide (PBI) was deposited by electrochemical polymerization, which showed reversible n-doping/dedoping processes at rather low potentials, accompanied by color changes from an orange red (neutral) state to a transparent (radical anion) state and further to an aquamarine (dianion) state.
ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc07962h