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Photochemical CO2 reduction in water using a co-immobilised nickel catalyst and a visible light sensitiserElectronic supplementary information (ESI) available: Synthetic procedures, catalyst characterisation and supporting photocatalytic and transient spectroscopic measurements. CCDC 1511267. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6cc08590c

A dye-sensitised CO 2 reduction photocatalyst that operates in water is reported. Transient spectroscopy demonstrates that the facile co-immobilisation of a Ru dye and a Ni CO 2 reduction electrocatalyst enables efficient on-particle electron transfer leading to photocatalytic activity that greatly...

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Bibliographic Details
Main Authors: Neri, Gaia, Forster, Mark, Walsh, James J, Robertson, C. M, Whittles, T. J, FarrĂ s, Pau, Cowan, Alexander J
Format: Article
Language:English
Online Access:Get full text
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Summary:A dye-sensitised CO 2 reduction photocatalyst that operates in water is reported. Transient spectroscopy demonstrates that the facile co-immobilisation of a Ru dye and a Ni CO 2 reduction electrocatalyst enables efficient on-particle electron transfer leading to photocatalytic activity that greatly exceeds the equivalent solution based system. Dye-sensitised photocatalytic CO 2 reduction in water using an immobilised Nickel catalyst operates with efficiencies greatly exceeding the equivalent solution based system.
ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc08590c