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Cyclodiphosphazanes: options are endless
Cyclodiphosphazanes, also known as diazadiphosphetidines, are saturated inorganic ring systems containing alternating trivalent phosphorus and nitrogen atoms. With a rigid planar structure and moderately stable P-N bonds, cyclodiphosphazanes have shown versatility not only in coordination chemistry...
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Published in: | Dalton transactions : an international journal of inorganic chemistry 2016, Vol.45 (31), p.12252-12282 |
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Main Author: | |
Format: | Article |
Language: | English |
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Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | Cyclodiphosphazanes, also known as diazadiphosphetidines, are saturated inorganic ring systems containing alternating trivalent phosphorus and nitrogen atoms. With a rigid planar structure and moderately stable P-N bonds, cyclodiphosphazanes have shown versatility not only in coordination chemistry as both neutral and anionic ligands but also as useful scaffolds in supramolecular chemistry, resulting in a plethora of molecules with interesting structural features. Recent reports on their utility in generating several 3D-coordination polymers including those with sodalite structures, cyclodiphosphazane based N-heterocyclic carbenes and stable biradicaloids highlight the versatility of these novel phosphorus-nitrogen cyclic compounds. This review describes mainly the coordination chemistry of cyclodiphosphazanes as neutral ligands and their applications besides recent advances in cyclodiphosph(
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)azane chemistry. The key points on the empirical model proposed to highlight the coordinating ability of cyclodiphosphazanes to build soft-soft MOFs and an analysis of pertinent structural features are also presented.
This short review describes the transition metal chemistry of cyclodiphosphazanes. |
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ISSN: | 1477-9226 1477-9234 |
DOI: | 10.1039/c6dt01121g |