C-H imidation: a distinct perspective of C-N bond formation

The direct imidation strategy proficiently constructs C-N bonds and creates the useful amine functional group in the molecular template. This review briefly discusses the synthetic methods developed for the direct imidation of unactivated C(sp 2 /sp 3 /sp)-H bonds. Transition-metal catalysts, metal-...

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Bibliographic Details
Published in:Organic & biomolecular chemistry 2017-02, Vol.15 (6), p.1282-1293
Main Authors: Rit, Raja K, Shankar, Majji, Sahoo, Akhila K
Format: Article
Language:English
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Summary:The direct imidation strategy proficiently constructs C-N bonds and creates the useful amine functional group in the molecular template. This review briefly discusses the synthetic methods developed for the direct imidation of unactivated C(sp 2 /sp 3 /sp)-H bonds. Transition-metal catalysts, metal-free processes, and/or photo-induced methods are invariably employed for accomplishing C-H imidation transformations. The contents summarized herein would benefit the research community to use the C-H imidation reactions for broad synthetic applications and to unravel novel C-N bond forming processes. The direct imidation strategy proficiently constructs C-N bonds and creates the useful amine functional group in the molecular template.
ISSN:1477-0520
1477-0539
DOI:10.1039/c6ob02162j